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Phosphorus-Based Polymers: From Synthesis to Applications: Volume 11
Author(s): Sophie Monge
- Publisher: Royal Society of Chemistry
- Publication Date: 22 May 2014
- Language: English
- Print length: 318 pages
- ISBN-10: 1849736464
- ISBN-13: 9781849736466
Book Description
A comprehensive overview of the synthesis of different phosphorus-containing polymers and their uses in biomedical, environmental and energy applications.
Editorial Reviews
Review
From the Back Cover
Phosphorus-containing (co)polymers are gaining wide appeal for many uses, from healthcare and medicine to energy and environmental applications. Phosphorus-Based Polymers is the first book dedicated to this topic and provides a comprehensive overview of the different polymers and their uses.
The first part of the book covers the synthesis and polymerisation of different phosphorus containing systems including phosphorus containing (meth)acrylate, (meth)acrylamide and viny or allyl monomers, as well as vinyl phosphonic acid, 2-methacryloyloxyethyl phosphorylcholine, poly(phosphoesters)and polyphosphazenes. The second part of the book contains specific chapters detailing different applications such as biomedical applications in dental materials, tissue engineering and drug delivery, metal complexation for anti-corrosion and wastewater purification materials, fire retardant additives and fuel cell membranes.
Written by expert researchers in the chemistry of phosphorus-containing polymers, this book is suitable for academic and industrial researchers interested in polymer and materials synthesis as well as their applications.
About the Author
Sophie Monge is assistant professor in Macromolecular Chemistry at the University of Montpellier 2, in the ICGM laboratory. She is an expert in controlled radical polymerization, especially atom transfer radical polymerization (ATRP) and reversible addition-fragmentation transfer polymerization (RAFT). This includes the synthesis of various molecules necessary for the polymerization reactions such as ligands, initiators, chain transfer agents, etc…and their characterization. An important field of her research deals with the synthesis and polymerization of phosphorus-containing polymers for various applications, in particular the biomedical field, and the complexation with metals.
Ghislain David is assistant professor in Macromolecular Chemistry at the National School of Chemistry of Montpellier, in the ICGM laboratory. His main research projects are in the field of phosphorus-containing polymers obtained either from synthesis and radical polymerizations of phosphorus-containing monomers or from post-modification of pre-made polymers. Thus he is an expert in organo-phosphorus chemistry aiming at synthesizing of new monomers and polymers having phosphonate moieties. His research interests concern the developments of such polymers for a large field of applications: membranes for fuel cells, anti-corrosive coatings and flame retardants.
Excerpt. © Reprinted by permission. All rights reserved.
Phosphorus-Based Polymers
From Synthesis to Applications
By Sophie Monge, Ghislain David
The Royal Society of Chemistry
Copyright © 2014 The Royal Society of Chemistry
All rights reserved.
ISBN: 978-1-84973-646-6
Contents
Chapter 1 Polymerization of Phosphorus-Containing (Meth)acrylate Monomers Sophie Monge, Benjamin Canniccioni, Ghislain David and Jean-Jacques Robin,
Chapter 2 Polymerization of Phosphorus-Containing (meth)acrylamide Monomers Sophie Monge, Alain Graillot and Jean-Jacques Robin,
Chapter 3 Phosphorus-Containing Vinyl or Allyl Monomers Ghislain David and Claire Negrell-Guirao,
Chapter 4 Synthesis and Polymerization of Vinylphosphonic Acid Lavinia Macarie and Gheorghe Ilia,
Chapter 5 2-Methacryloyloxyethyl Phosphorylcholine Polymers Kazuhiko Ishihara and Kyoko Fukazawa,
Chapter 6 Polyphosphoesters Véronique Montembault and Laurent Fontaine,
Chapter 7 Phosphazene High Polymers Harry R. Allcock,
Chapter 8 Phosphorus-Based Monomers Used for Dental Application Norbert Moszner and Yohann Catel,
Chapter 9 Biomedical Applications of Phosphorus-Containing Polymers Edeline Wentrup-Byrne, Shuko Suzuki and Lisbeth Grøndahl,
Chapter 10 Complexation with Metals: Anticorrosion Phosphorus-Containing Polymer Coatings Ghislain David and Claire Negrell-Guirao,
Chapter 11 Use of Phosphorus-Containing Polymers for the Removal of Metal Ions from Wastewater Lavinia Lupa, Adriana Popa and Gheorghe Ilia,
Chapter 12 Flame Retardancy of Phosphorus-Containing Polymers Rodolphe Sonnier, Laurent Ferry and José-Marie Lopez-Cuesta,
Chapter 13 Proton Conducting Phosphonated Polymers and Membranes for Fuel Cells Bahar Bingöl and Patric Jannasch,
Subject Index,
CHAPTER 1
Polymerization of Phosphorus-Containing (Meth)acrylate Monomers
SOPHIE MONGE, BENJAMIN CANNICCIONI, GHISLAIN DAVID AND JEAN-JACQUES ROBIN
Institut Charles Gerhardt de Montpellier, UMR5253 CNRS-UM2-ENSCM-UM1, Equipe Ingénierie et Architectures Macromoléculaires, Université Montpellier II, cc1702, Place Eugène Bataillon, 34095, Montpellier, France
1.1 Introduction
In recent years, phosphorus-based polymers have been widely studied as they exhibit very unusual and interesting properties. Whereas the ester forms are the most available compounds, monoacids and diacids can be easily obtained under mild conditions with the use of bromotrimethylsilane, opening the way to a wide range of polymers showing different properties. The latter can be explained in part by the ionization potential of phosphonic acids, which is intermediate between that of sulfonic and carboxylic acids due to their intermediate pKa.
Phosphorus-containing materials can be employed for a wide range of technological applications. For instance, they are extensively used in industry, notably to bind metals. Indeed, phosphorus-based materials show interesting complexing properties and are used as dispersants, corrosion inhibiting agents, or for preventing deposit formation. They are also involved in flame retardancy, where phosphorus is known to be particularly useful. An important industrial application deals with their use in the biomedical field, as they are biodegradable, blood compatible, show reduced protein adsorption, and lead to strong interactions with dentin, enamel, or bones. As a consequence, various syntheses of monomers and polymers are carried out following different procedures: (i) introduction of the phosphorinated moieties onto polymers by (co)polymerization of monomers bearing the p
